Chromium and nickel in electroplating baths. Complexometric reactions: [. ] +. + Coulometric titration is mainly employed for low water content determination. Excel will automatically append the file to the file. In concentration of Ca in ppm determined by colorimetry, EDTA titration and atomic Chromium was determined in a water sample by the multiple standard additions. Szekeres, László. (). Determination of chromium by EDTA titration. Microchemical Journal – MICROCHEM J. /X(72)

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The second titration uses.

Add 1—2 drops of indicator and titrate with a standard solution of EDTA until the red-to-blue end point is reached Figure 9. Calculate pM values chomium the equivalence point by determining the concentration of unreacted metal ions.

The calculations are straightforward, as we saw earlier. Compare your sketches to the calculated titration curves from Practice Exercise 9. After the equivalence point the absorbance remains essentially unchanged. In this case the interference is the possible precipitation of CaCO 3 at a pH of The sample, therefore, contains 4. The scale of operations, accuracy, precision, sensitivity, time, and cost of a complexation titration are similar to those described earlier for acid—base titrations.

The third titration uses. Calculate pM at the equivalence point using the conditional formation constant. For example, after adding 5.

Finding the End point with an Indicator Most indicators for complexation titrations are organic dyes—known as metallochromic indicators —that form stable complexes with metal ions. The quantitative relationship between the titrand and the titrant is determined by the stoichiometry of the titration reaction.


If the metal—indicator complex is too weak, however, the end point occurs before we reach the equivalence point.

EDTA, which is shown in Figure 9. We also will learn how to quickly sketch a good approximation of any complexation titration curve using a limited number of simple calculations.

Using these values, the conditional formation constant is. First, however, we discuss the selection and standardization of complexation titrants.

Calculate pM after the equivalence point using the conditional formation constant.

9.3: Complexation Titrations

Note that in this example, the analyte is the titrant. The formation constant for CdY 2— in equation 9. After adding calmagite as an indicator, the solution was titrated with the EDTA, requiring Note The best way to appreciate the theoretical and practical details discussed in tutration section is to carefully examine a typical complexation titrimetric method. Procedure Select a volume of sample requiring less than 15 mL of titrant to keep the analysis time under 5 minutes and, if necessary, dilute the sample to 50 mL with distilled water.

Note Our derivation here is general and applies to any complexation titration using EDTA as a titrant. For example, as shown in Figure 9.

Complexation Titrations – Chemistry LibreTexts

Complexation titrations, however, are more selective. Finally, a third See Chapter 11 for more details about ion selective electrodes.

Report the weight percents of Ni, Fe, and Cr in the alloy. As shown in the following example, we can easily extended this calculation to complexation reactions using other titrants. After filtering and rinsing the precipitate, it is dissolved in Recall that an acid—base titration curve for a diprotic weak acid has a single end point if its two K a values are not sufficiently different.


Ethylenediaminetetraacetic acid, or EDTA, is an aminocarboxylic acid.

The resulting metal—ligand complex, in which EDTA forms a cage-like structure around the metal ion Figure 9. Calculate the conditional formation constant for the metal—EDTA complex.

extraction of copper by edta

The availability of a ligand that gives a single, easily identified end point made complexation titrimetry a practical analytical method. As shown in Table 9. For a titration using EDTA, the stoichiometry is always 1: The specific form of EDTA filetypr reaction 9. The analogous result for a complexation titration shows the change in pM, where M is the metal ion, as a function of the volume of EDTA. If the metal—indicator complex is too strong, the change in color occurs after the equivalence point.

Selection and Standardization of Titrants EDTA is a versatile titrant that can be used to analyze virtually all metal ions. To do so we need to know the shape of a complexometric EDTA titration curve.